| Luminescent Tetranuclear Copper（I） Phenylacetylide Complex with Cyclohexyl Isocyanide |
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| 引用本文： | 施林熙,张礼仪,陈忠宁.Luminescent Tetranuclear Copper（I） Phenylacetylide Complex with Cyclohexyl Isocyanide[J].结构化学,2005,24(1):13-16. |
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| 作者姓名： | 施林熙 张礼仪 陈忠宁 |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
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| 基金项目： | This work was supported by NSF of Fujian Province (E0420002 and E0310029) |
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| 摘 要： | 1INTRODUCTIONThechemistryofmetalalkynylcomplexeshasattractedmuchattentioninrecentyearsduetothespecificinterestinstructuraltopologyandopticalproperties1～6].Ithasbeendemonstratedthatoneofthefeasiblestrategiestoattainoligomericmetalalky-nylcomplexesistodepolymerizepolymericspeciesofmetalalkynylsbyusingorganicligandssuchasphosphines7～11]andisocyanides12～14].Insomecases,simplemetal-containingcomponentsarealsoavail-abletodepolymerizethepolymericmetalalkynyl,formingalkynyl-bridgedheterometa…
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| 关 键 词： | 四核铜（I）苯基乙炔配合物 环已基异腈 [Cu（C≡CPh）]n 解聚 发光性 |
Luminescent Tetranuclear Copper(I) Phenylacetylide Complex with Cyclohexyl Isocyanide |
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| SHI Lin Xi,ZHANG Li Yi,CHEN Zhong-Ning.Luminescent Tetranuclear Copper(I) Phenylacetylide Complex with Cyclohexyl Isocyanide[J].Chinese Journal of Structural Chemistry,2005,24(1):13-16. |
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| Authors: | SHI Lin Xi ZHANG Li Yi CHEN Zhong-Ning |
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| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
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| Abstract: | Depolymerizing copper(I) phenylacetylide Cu(C(CPh)]n with cyclohexyl isocy- anide (CNCy) gave a tetranuclear copper(I) complex Cu4(CNCy)4(μ-η1-C≡CPh)2(μ3-η1,η1, η2-C≡CPh)2. Crystal data: C30H32Cu2N2, Mr = 547.66, space group P1, a = 8.6448(1), b = 11.5772(2), c = 14.6666(4) (A), α = 88.387(2), β = 86.826(2), γ = 68.222(1)°, V = 1360.97(5) (A)3, Z = 2, F(000) = 568, Dc = 1.336 g/cm3, μ = 1.582 mm-1, the final R = 0.0629 and wR = 0.1282 for 3257 observed reflections with I > 2σ(I). The phenylacetylide adopts μ-η1 and μ3-η1,η1,η2 bonding modes. The compound shows intense luminescence in the solid state. |
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| Keywords: | acetylide copper isocyanide luminescence |
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