Synthesis and Crystal Structure of 2-Benzoyl Pyridine Thiosemicarbazato Palladium(II) Chloride |
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作者姓名: | 刘泽华 王守兴 段春迎 游效曾 |
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作者单位: | Coordination Chemistry Institute,State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093 |
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摘 要: | 1 INTRODUCTIONRecently,thiosemicarbazoneshaveattractedmuchattentionwithinbiologicalsystemandcoordinationchemistry.1-3]IthasbeenpostulatedthatmanyNheterocycliccarbaldehydethiosemicarbazonesactastridentateN2Sligandswhichbondtoironorcopperinthesynthesisofp…
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Synthesis and Crystal Structure of 2 Benzoyl Pyridine Thiosemicarbazato Palladium(II) Chloride |
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Abstract: | The title complex,2-benzoyl pyridine thiosemicarbazato palladium(Ⅱ)chloride C13H11N4SPdCl,Mr=379.17],crystallizes in monoclinic,space group C2/c with a=12.1061(5),b=21.877(3),c=11.4832(6)A,β=108.29(9)°,V=2887.7(4)A3,Z=8,Dc=1.827g/cm3; μ=1.608cm-1 and F(000)=1568.R=0.0281 and wR=0.0684 for 1446 reflections with I > 2σ(Ⅰ).X-ray crystal structure analysis revealed that the coordination geometry of Pd atom is a distorted square plane with two Pd- N bonds,one Pd - S bond and one Pd - Cl bond.The Schiff-base ligand loses a proton from its tautomeric thiol form and coordinates to the Pd atom via the mercapto sulfur and theβ-nitrogen atoms. |
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Keywords: | crystal structure palladium complex | |