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多孔材料化学:从无机微孔化合物到金属有机多孔骨架
引用本文:林之恩,杨国昱.多孔材料化学:从无机微孔化合物到金属有机多孔骨架[J].结构化学,2004,23(12):1388-1398.
作者姓名:林之恩  杨国昱
作者单位:中国科学院福建物质结构研究所,结构化学国家重点实验室,福州,350002
基金项目:国家自然科学基金资助项目(20171045、20271050 及 20473093),福建省自然科学基金(E0210029),中科院“ 引进国外杰出人才” 专项基金资助
摘    要:本文主要从无机微孔化合物和金属有机多孔骨架的合成化学和结构化学这两方面来介绍多孔材料化学的研究进展。多孔材料是一类具有规则孔结构的固态化合物,它们在催化、分离、离子交换等工业领域有着广泛的应用。硅铝酸盐是最为人们所熟知的微孔分子筛,经过半个多世纪的发展,人们又相继开发出磷酸盐、砷酸盐、锗酸盐、亚磷酸盐、硫酸盐、亚硒酸盐以及金属硫化物等类沸石无机微孔化合物。近十多年来,配位聚合物与金属有机多孔骨架开始大量兴起,为微孔化合物的多样化与组成的复杂性增添了新的领域。

关 键 词:多孔材料  无机微孔化合物  金属有机多孔骨架

Chemistry of Porous Materials:from Microporous Inorganic Solids to Metal-organic Frameworks
LIN Zhi-En YANG Guo-Yu.Chemistry of Porous Materials:from Microporous Inorganic Solids to Metal-organic Frameworks[J].Chinese Journal of Structural Chemistry,2004,23(12):1388-1398.
Authors:LIN Zhi-En YANG Guo-Yu
Abstract:In this short review, the progress in the synthetic and structural chemistry of porous materials, including microporous inorganic solids and metal-organic frameworks, will be presented. Porous materials are a class of solids with regular pores or voids. They may find widespread applications in some industrial processes, such as catalysis, separation and ion-exchange. Zeolites (aluminosilicates) are the most well-known microporous molecular sieves. During the past decades, a huge number of new zeolite-like inorganic solids like phosphates, arsenates, germanates, phosphite, sulfate and supertetrahedral sulfides have been synthesized and characterized. Recently, the researches on coordination polymers and metal-organic frameworks are very intense, which enrich the diverse structures and various stoichiometries of microporous materials.
Keywords:porous material  microporous inorganic solid  metal-organic framework  
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