| Synthesis and Crystal Structure of {4-[2-（9- Hexyl-9H-carbazol-3-yl）vinyl]phenyl} Dimethylamine |
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| 作者姓名： | WANG Hong-Li XU Wen-Yuan WANG Ding-Li ZHANG Bin WU Hong |
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| 作者单位： | [1]Department of Chemistry, Central China Normal University, Wuhan 430079, China [2]Department of Physics, Wuhan University, Wuhan 430072, China [3]Accelink Technologies Co., Ltd, Wuhan, Hubei 430074, China |
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| 摘 要： | The title compound {4-2-(9-hexyl-9H-carbazol-3-yl)vinyl]phenyl} dimethylamine has been synthesized by the well known Wittig reaction, and its crystal structure was determined by single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group P21/c with a = 47.87(2), b = 10.222(4), c = 9.612(4) , β = 92.401(9)o, V = 4699(3) 3, Z = 8, C28H32N2, Mr = 396.56, Dc = 1.121 g/cm3, F(000) = 1712 and μ(MoKa) = 0.065 mm-1. The final R and wR are 0.0793 and 0.1983, respectively for 3524 observed reflections with I > 2σ(I). In the title compound, the bond lengths are normal, and the crystal is stabilized by Van der Waals’ forces.
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| 关 键 词： | 维蒂希反应 晶体结构 N-己基-3-甲酸基咔唑 杂环化合物 |
| 收稿时间： | 2006-09-05 |
| 修稿时间： | 2006-09-052006-12-30 |
Synthesis and Crystal Structure of {4-[2-(9- Hexyl-9H-carbazol-3-yl)vinyl]phenyl} Dimethylamine |
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| WANG Hong-Li XU Wen-Yuan WANG Ding-Li ZHANG Bin WU Hong.Synthesis and Crystal Structure of {4-[2-(9- Hexyl-9H-carbazol-3-yl)vinyl]phenyl} Dimethylamine[J].Chinese Journal of Structural Chemistry,2007,26(6):691-694. |
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| Authors: | WANG Hong-Li XU Wen-Yuan WANG Ding-Li ZHANG Bin WU Hong |
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| Abstract: | The title compound {4-2-(9-hexyl-9H-carbazol-3-yl)vinyl]phenyl} dimethylamine has been synthesized by the well known Wittig reaction, and its crystal structure was determined by single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group P21/c with a = 47.87(2), b = 10.222(4), c = 9.612(4)(A), β = 92.401(9)°, V = 4699(3)(A)3, Z = 8, C28H32N2, Mr = 396.56, Dc = 1.121 g/cm3, F(000) = 1712 and μ(MoKa) = 0.065 mm-1. The final R and wR are 0.0793 and 0.1983, respectively for 3524 observed reflections with Ⅰ＞ 2σ(Ⅰ). In the title compound, the bond lengths are normal, and the crystal is stabilized by Van der Waals' forces. |
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| Keywords: | Wittig reaction crystal structure N-hexyl-3-formylcarbazole Crystal Structure Synthesis vinyl forces crystal structure Waals bond lengths normal final space group diffraction analysis dimethylamine synthesized known Wittig reaction compound |
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