| A New Two-dimensional Copper（II） Complex with p-PhDTA Bridges |
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| 作者姓名： | ZHENG Lei NI Zhong-Hai LI Wen-Lu ZHANG Li-Fang GE Chun-Hua CUI Ai-Li KOU Hui-Zhong |
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| 作者单位： | Department of Chemistry Tsinghua University，Department of Chemistry，Tsinghua University，Department of Chemistry，Tsinghua University，Department of Chemistry，Tsinghua University，Department of Chemistry，Tsinghua University，Department of Chemistry，Tsinghua University，Department of Chemistry，Tsinghua University，Beijing 100084 China，Beijing 100084 China，Beijing 100084 China，Beijing 100084 China，Beijing 100084 China，Beijing 100084 China，Beijing 100084 China |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China （No. 20671055） |
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| 摘 要： | A new p-PhDTA bridged Cu（II） complex Cu2（p-PhDTA）（DMSO）2]·4DMSO （p-PhDTA = p-phenylenediamine-N,N,N,N＇-tetraacetic acid） has been synthesized and structurally characterized. The crystal belongs to orthorhombic, space group Pca21 with a = 19.572（4）, b = 19.552（4）, c = 10.156（2）A, C26H48N2O14CU2S6, Mr = 932.10, V = 3886.4（13）A3, Z = 4, Dc = 1.593 g/cm^3, F（000） = 1936, λ（MoKa） = 0.71073A,μ = 1.480, R = 0.0487 and wR = 0.1151 for 8464 observed reflections （I 〉2σ（I））. In the complex, the oxygen atoms of carboxylate of p-PhDTA connect the Cu atoms in a syn-anti type, giving one-dimensional chains which are further linked by the benzene groups ofp-PhDTA to form a novel two-dimensional structure.
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| 关 键 词： | 铜(Ⅱ)配位化合物 二维结构 配位聚合体 羧酸酯 |
A New Two-dimensional Copper(II) Complex with p-PhDTA Bridges |
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| ZHENG Lei NI Zhong-Hai LI Wen-Lu ZHANG Li-Fang GE Chun-Hua CUI Ai-Li KOU Hui-Zhong.A New Two-dimensional Copper(II) Complex with p-PhDTA Bridges[J].Chinese Journal of Structural Chemistry,2008,27(7):793-796. |
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| Authors: | ZHENG Lei NI Zhong-Hai LI Wen-Lu ZHANG Li-Fang GE Chun-Hua CUI Ai-Li KOU Hui-Zhong |
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| Institution: | Department of Chemistry, Tsinghua University, Beijing 100084, China |
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| Abstract: | A new p-PhDTA bridged Cu(II) complex Cu2(p-PhDTA)(DMSO)2]·4DMSO (p-PhDTA = p-phenylenediamine-N,N,N',N'-tetraacetic acid) has been synthesized and structurally cha-racterized. The crystal belongs to orthorhombic, space group Pca21 with a = 19.572(4), b = 19.552(4), c = 10.156(2) , C26H48N2O14Cu2S6, Mr = 932.10, V = 3886.4(13) 3, Z = 4, Dc = 1.593 g/cm3, F(000) = 1936, λ(MoKα) = 0.71073 , μ = 1.480, R = 0.0487 and wR = 0.1151 for 8464 observed reflections (I >2σ(I)). In the complex, the oxygen atoms of carboxylate of p-PhDTA connect the Cu atoms in a syn-anti type, giving one-dimensional chains which are further linked by the benzene groups of p-PhDTA to form a novel two-dimensional structure. |
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| Keywords: | copper two-dimensional coordination polymer carboxylate |
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