| A Chinese Lantern-like 2D Cu(Ⅱ) Coordination Polymer Constructed by Bis-imidazole and Dicarboxylate Co-ligands: Synthesis,Crystal Structure and Photocatalytic Activity |
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| 引用本文： | 卢久富,赵娟,赵蔡斌,于小虎,SOUMENDRA Kumar Roy,岳思羽,李丽,周科,靳玲侠,葛红光.A Chinese Lantern-like 2D Cu(Ⅱ) Coordination Polymer Constructed by Bis-imidazole and Dicarboxylate Co-ligands: Synthesis,Crystal Structure and Photocatalytic Activity[J].结构化学,2020,39(2):321-328. |
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| 作者姓名： | 卢久富 赵娟 赵蔡斌 于小虎 SOUMENDRA Kumar Roy 岳思羽 李丽 周科 靳玲侠 葛红光 |
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| 作者单位： | Shaanxi Key Laboratory of Catalysis |
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| 基金项目： | Key scientific research project of education department of Shaanxi province;and the Science Foundation of Shaanxi University of Technology;Shaanxi provincial science and technology department project;Supported by the team of syngas catalytic conversion of Shaanxi University of Technology,the National Natural Science Foundation of China |
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| 摘 要： | A new Cu(II) coordination polymer, {Cu(1,3-BIP)(TFBDC)]·DMF}n(1,1,3-BIP is a 1,3-bis(imidazole)propane, and H2TFBDC is 2,3,5,6-tetrafluoroterephthalic acid) was prepared under solvothermal conditions and characterized by single-crystal and powder X-ray diffraction, IR spectra, thermogravimetric analyses and elemental analyses. The single-crystal X-ray diffraction reveals that metal coordination polymer 1(MCP 1) shows a two-dimensional sheet layer structure, which is further reinforced through strong intermolecular hydrogen bonding to form a 3 D supramolecular framework. Furthermore, the photocatalytic experiment result indicates the degradation ratios of methyl orange(MO) reach 83.4% within 180 minutes when MCP 1 acts as catalyst.
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| 关 键 词： | SOLVOTHERMAL SYNTHESIS crystal structure Cu(II)coordination polymer photocatalytic activity |
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