| Crystal Structure of Catena-poly-[2,2'-bisbenzimidazole Mn(Ⅱ)-μ-Benzene-1,3-dicarboxylato] |
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| 引用本文： | 吕明,姜大雨,孙艳涛,王丽,王家军,高广刚.Crystal Structure of Catena-poly-[2,2'-bisbenzimidazole Mn(Ⅱ)-μ-Benzene-1,3-dicarboxylato][J].结构化学,2010,29(2):265-269. |
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| 作者姓名： | 吕明 姜大雨 孙艳涛 王丽 王家军 高广刚 |
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| 作者单位： | Chemistry;Department;Jilin;Normal;University; |
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| 基金项目： | supported by Jilin Normal University |
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| 摘 要： | The title complex,(BBI)Mn(BDC)]n 1(BBI = 2,2'-bisbenzimidazole(C14H10N4),BDC=benzene-1,3-dicarboxylate dianion(C8H10O4)),crystallizes in the monoclinic system,space group C2/c,with a=17.822(8),b=16.181(7),c=13.355(6),β=92.112(5)°,V=3848.67(304)3,Z=8,C22H14MnN4O4,Mr=453.31,Dc=1.565 g/cm3,F(000)=1848,μ=0.725 mm-1,S=1.000,the final R=0.0310 and wR=0.0589.1 contains hydrogen bonds and π-π stacking interactions between the neighboring aryl-ring of BBI's,which helps to form a three-dimensional crystal structure.
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| 关 键 词： | 三维晶体结构 锰（Ⅱ） 晶体群 π-π堆积作用 苯 单斜晶系 配合物 BDC |
Crystal Structure of Catena-poly-[2,2'bisbenzimidazole Mn(Ⅱ)-μ-Benzene-1,3-dicarboxylato] |
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| LV Ming,JIANG Da-Yu,SUN Yan-Tao,WANG Li,WANG Jia-Jun,GAO Guang-Gang.Crystal Structure of Catena-poly-[2,2''bisbenzimidazole Mn(Ⅱ)-μ-Benzene-1,3-dicarboxylato][J].Chinese Journal of Structural Chemistry,2010,29(2):265-269. |
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| Authors: | LV Ming JIANG Da-Yu SUN Yan-Tao WANG Li WANG Jia-Jun GAO Guang-Gang |
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| Institution: | Chemistry Department of Jilin Normal University, Siping 136000, China |
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| Abstract: | The title complex, (BBI)Mn(BDC)]_n 1(BBI = 2,2'-bisbenzimidazole (C_(14)H_(10)N_4),BDC = benzene-1,3-dicarboxylate dianion (C_8H_(10)O_4)), crystallizes in the monoclinic system, space group C2/c, with α= 17.822(8), b=16.181(7), c = 13.355(6) (A), β = 92.112(5)°, V= 3848.67(304)(A)~3, Z = 8, C_(22)H_(14)MnN_4O_4, M_r = 453.31, D_c = 1.565 g/cm~3, F(000) = 1848,μ = 0.725 mm~(-1), S =1.000, the final R = 0.0310 and wR = 0.0589. 1 contains hydrogen bonds and π-π stacking interactions between the neighboring awl-ring of BBI's, which helps to form a three-dimensional crystal structure. |
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| Keywords: | 2 2'-bisbenzimidazole benzene-1 3-dlcarboxylate manganese(H) complex single-crystal structure TG |
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