| Synthesis and Crystal Structure of Tert-butyl 4-[(E)-4-(1,3-Dioxo-1,3-dihydro-2H-isoindol-2-yl)-1-butenyl] Benzoate |
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| 作者姓名： | 张新歌 张慧杰 王瑱 李朝兴 |
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| 作者单位： | Institute of Polymer Chemistry Nankai University，Institute of Polymer Chemistry Nankai University，Institute of Polymer Chemistry Nankai University，Institute of Polymer Chemistry Nankai University，Tianjin 300071 China，Tianjin 300071 China，Tianjin 300071 China，Tianjin 300071 China |
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| 摘 要： | 1 INTRODUCTION Phthalimide and its derivatives are synthetic mate- rials, which are widely used as important chemical intermediates of biosensors1] and many drugs such as Citalopran2], luminal3], Beta-Lactam4] and the No. three generation quinolones5], and they have been identified as active groups of some drugs and chemical luminescence reagents6, 7]. Tert-butyl 4- (E)-4-(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)-1- butenyl] benzoate is an intermediate of a new type of insulin sen…
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Synthesis and Crystal Structure of Tert-butyl 4-[(E)-4-(1,3 -Dioxo-1,3-dihydro-2H-isoindol-2-yl)-1-butenyl] Benzoate |
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| ZHANG Xin-Ge,ZHANG Hui-Jie,WANG Zhen,LI Chao-Xing.Synthesis and Crystal Structure of Tert-butyl 4-[(E)-4-(1,3-Dioxo-1,3-dihydro-2H-isoindol-2-yl)-1-butenyl] Benzoate[J].Chinese Journal of Structural Chemistry,2006,25(3). |
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| Authors: | ZHANG Xin-Ge ZHANG Hui-Jie WANG Zhen LI Chao-Xing |
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| Abstract: | The title compound tert-butyl 4-(E)-4-(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)- 1-butenyl] benzoate has been synthesized and characterized by X-ray crystallography. It crystallizes in monoclinic, space group C2/c with a = 14.875(3), b = 8.9796(13), c = 34.736(6)(A), β = 95.981(4)°, V = 4614.4(14)(A)3, Z = 8, Dc = 1.213 g/cm3, F(000) = 1792, μ(MoKa) = 0.084 mm-1, R = 0.0602 and wR = 0.1445 for 4613 unique reflections with 2272 observed ones (I > 2σ(I)). The results of crystal structure determination show that the title compound has a layer structure, and the two benzene rings in molecule are parallel to each other. |
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| Keywords: | tert-butyl 4-[(E)-4-(1 3-dioxo-1 3-dihydro-2H-isoindol-2-yl)-1-butenyl]benzoate synthesis crystal structure |
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