One Pillared Layered Zn(Ⅱ) Coordination Compound Based on 2,6-Naphthalenedicarboxylic Acid: Synthesis,Structure and Luminescent Property |
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引用本文: | 李亚敏,吴莹莹,李海燕,赵晓伟,金邻豫,党东宾.One Pillared Layered Zn(Ⅱ) Coordination Compound Based on 2,6-Naphthalenedicarboxylic Acid: Synthesis,Structure and Luminescent Property[J].结构化学,2019,38(5):761-768,669. |
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作者姓名: | 李亚敏 吴莹莹 李海燕 赵晓伟 金邻豫 党东宾 |
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基金项目: | the National Natural Science Foundation of China;Young Backbone Teacher Project of Henan Colleges and Universities;Foundation of Henan University |
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摘 要: | One new pillared layered zinc hydroxide {Zn4(OH)6(ndc)·2(H2O)}n,(H2 ndc =2,6-na-phthalenedicarboxylic acid) has been achieved under hydrothermal conditions by using2,6-na-phthalenedicarboxylic acid, 2,4-diami-6-phenyl-1,3,5-triazine as well as Zn(OAc)2·2 H2O,and structurally characterized by X-ray single-crystal diffraction, IR spectra, elemental analysis,powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA). The X-ray single-crystal diffraction proves that the title compound is in monoclinic system, space group P21/c with a =16.362(8), b = 9.324(5), c = 5.364(3)A,β= 99.081(9)°, V = 808.1(7)A^3, Dc = 2.522 g/cm3, Mr =613.73, Z = 2, F(000)= 608,μ= 5.935 mm-1, GOOF = 1.050, R = 0.0469 and wR(Ⅰ> 2σ(Ⅰ))=0.1291. In the title compound, the tetrahedral and octahedral zinc atoms are connected by μ3-OH groups to form zinc hydroxide inorganic layers extending parallel to the bc-plane. The adjacent layers are pillared by the connection of Zn2 atoms with ndc2-ligands to construct a three-dimensional(3D) structure;meanwhile, the interactions of five hydrogen bonds make the 3D network structure more stable. Furthermore, the title compound exhibits luminescent property at solid state.
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关 键 词: | PILLARED layer zinc HYDROXIDE naphthalenedicarboxylic acid LUMINESCENT property |
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