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A Dinuclear Cu(Ⅱ)-based Coordination Framework with Two-fold Interpenetrated 3D pcu Topology Displaying Catalytic Activity
引用本文:明春伦,马培娟,李光跃,崔广华.A Dinuclear Cu(Ⅱ)-based Coordination Framework with Two-fold Interpenetrated 3D pcu Topology Displaying Catalytic Activity[J].结构化学,2014,33(9):1339-1345.
作者姓名:明春伦  马培娟  李光跃  崔广华
作者单位:College of Chemical Engineering, Hebei United University, Tangshan, Hebei 063009, China
基金项目:supported by the Excellent Youth Fund of Hebei Province Department of Education(Y2012010)
摘    要:A new Cu(Ⅱ) coordination polymer, Cu2(mip)2(bmix)]n(bmix = 1,4-bis(2-methylimidazole-1-ylmethyl)benzene, H2 mip = 5-methylisophthalic acid), has been hydrothermally synthesized and characterized by elemental analyses, IR, TGA and single-crystal X-ray diffraction. The title compound belongs to the triclinic system, space group P1 with a = 9.435(5), b = 12.241(6), c = 13.666(6), β = 94.396(8)o, V = 1565.5(13) 3, Z = 2, C34H30Cu2N4O8, Mr = 749.70, Dc = 1.590 g/cm3, μ = 1.419 mm-1 and F(000) = 768. The title metal-organic coordination polymer exhibits the first two-fold interpenetrated pcu topological structure assembled by two types of dinuclear copper(Ⅱ) clusters and a flexible bis(imidazole)-based ligand. In addition, the fluorescence and catalytic performances of the complex for the degradation of Congo red azo dye in Fenton-like process were presented.

关 键 词:拓扑结构  催化性能  双核铜  PCU  显示  2-甲基咪唑  单晶X射线衍射  类Fenton

A Dinuclear Cu(Ⅱ)-based Coordination Framework with Two-fold Interpenetrated 3D pcu Topology Displaying Catalytic Activity
MING Chun-Lun , MA Pei-Juan , LI Guang-Yue , CUI Guang-Hua.A Dinuclear Cu(Ⅱ)-based Coordination Framework with Two-fold Interpenetrated 3D pcu Topology Displaying Catalytic Activity[J].Chinese Journal of Structural Chemistry,2014,33(9):1339-1345.
Authors:MING Chun-Lun  MA Pei-Juan  LI Guang-Yue  CUI Guang-Hua
Institution:College of Chemical Engineering, Hebei United University, Tangshan, Hebei 063009, China
Abstract:catalysis, copper(II) complex, flexible bis(imidazole), fluorescence property
Keywords:catalysis  copper(Ⅱ) complex  flexible bis(imidazole)  fluorescence property
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