| Two Ion-pair Complexes Constructed by[M（mnt）2]n- （M=Ni,Co,mnt = Maleonitriledithiolate）:Syntheses,Characterization and Thermal Stability |
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| 引用本文： | 闫卫红,姬鄂豫,申明乐,李朝艳,李霞,徐雪丽.Two Ion-pair Complexes Constructed by[M（mnt）2]n- （M=Ni,Co,mnt = Maleonitriledithiolate）:Syntheses,Characterization and Thermal Stability[J].结构化学,2015(2):306-312. |
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| 作者姓名： | 闫卫红 姬鄂豫 申明乐 李朝艳 李霞 徐雪丽 |
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| 作者单位： | Nanyang Key Laboratory of Industrial Microbiology, School of Biology and Chemistry Engineering, Nanyang Institute of Technology |
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| 基金项目： | Supported by Science & Technology Research Projects of Henan Provincial Education Department(14B150035) |
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| 摘 要： | Two new ion-pair complexes Co(BBP)2]2Ni(mnt)2]Cl2·4DMF·2H2O(1, BBP =2,6-bis(benzimidazol-2'-yl) pyridine, mnt = maleonitriledithiolate) and (Py)2CH2]Co(mnt)2]2·4DMF(2) have been synthesized and characterized by elemental analyses, IR spectroscopy,thermogravimetric analyses and single-crystal X-ray diffraction. X-ray diffraction studies show that complex 1 crystallizes in monoclinic, space group P21/c. The crystal of 2 belongs to a triclinic system with space group P1. Due to the hydrogen bonding interactions, anions and cations formed the mixed packing in complex 1 while the anions and cations formed segregated columns in 2. In addition, thermogravimetric analyses of the two complexes are also investigated.
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| 关 键 词： | maleonitriledithiolate crystal structures hydrogen-bond |
Two Ion-pair Complexes Constructed by[M(mnt)_2]~(n-) (M=Ni,Co,mnt = Maleonitriledithiolate):Syntheses,Characterization and Thermal Stability |
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| YAN Wei-Hong;JI E-Yu;SHEN Ming-Le;LI Zhao-Yan;LI Xia;XU Xue-Li.Two Ion-pair Complexes Constructed by[M(mnt)_2]~(n-) (M=Ni,Co,mnt = Maleonitriledithiolate):Syntheses,Characterization and Thermal Stability[J].Chinese Journal of Structural Chemistry,2015(2):306-312. |
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| Authors: | YAN Wei-Hong;JI E-Yu;SHEN Ming-Le;LI Zhao-Yan;LI Xia;XU Xue-Li |
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| Institution: | YAN Wei-Hong;JI E-Yu;SHEN Ming-Le;LI Zhao-Yan;LI Xia;XU Xue-Li;Nanyang Key Laboratory of Industrial Microbiology, School of Biology and Chemistry Engineering, Nanyang Institute of Technology; |
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