| Crystal Structure of a Mn(Ⅱ) Coordination Polymer:[Mn(TP)(TBZH)_(2n)(TBZH=Thiabendazole,TP=Terephthalic Acid) |
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| 引用本文： | 王家军,崔运成,刘力辉,黄艳菊,吕明,李传碧,高广刚.Crystal Structure of a Mn(Ⅱ) Coordination Polymer:[Mn(TP)(TBZH)_(2n)(TBZH=Thiabendazole,TP=Terephthalic Acid)[J].结构化学,2010,29(2):240-244. |
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| 作者姓名： | 王家军 崔运成 刘力辉 黄艳菊 吕明 李传碧 高广刚 |
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| 作者单位： | Chemistry;Department;Jilin;Normal;University; |
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| 基金项目： | supported by Siping Sci-tech Development Planning Project (No 2005012) |
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| 摘 要： | The structure of a manganese(Ⅱ) polymer,Mn(TP)(TBZH)]2n 1(TBZH=thiabendazole,TP=terephthalic acid),has been determined by X-ray crystallography and characterized by elemental analysis,IR spectrum and thermogravimetric analysis.It crystallizes in the orthorhombic system,space group Pbcn with a=12.7813(12),b=10.7544(10),c=20.1270(19) ,V=2766.6(4)3,Z=8,C14H9Mn0.50N3O2S,Mr=310.77,Dc=1.492g/cm3,F(000)=1268,μ=0.674 mm-1 and S=1.064.The 1-D chain architecture of 1 is constructed from terephthalic acid and manganese atoms.Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to form a 3-D supramo-lecular structure.
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| 关 键 词： | 对苯二甲酸 锰（Ⅱ） 配位聚合物 晶体结构 噻菌灵 总磷 π-π堆积作用 X射线晶体学 |
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