| 含固氮酶钼微环境结构单元O_3MoS_3的Mo－S，Mo－Fe－S化合物的研究 |
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| 引用本文： | 庄伯涛,黄梁仁,兰安建,何玲洁,潘炳华,余佩华.含固氮酶钼微环境结构单元O_3MoS_3的Mo－S，Mo－Fe－S化合物的研究[J].结构化学,1995(3). |
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| 作者姓名： | 庄伯涛 黄梁仁 兰安建 何玲洁 潘炳华 余佩华 |
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| 作者单位： | 中国科学院福建物质结构研究所 |
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| 基金项目： | 国家自然科学基金,国家攀登计划基金 |
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| 摘 要： | 研究了含固氮酶钼微环境Ｏ_３ＭｏＳ_３结构单元四个系列化合物［Ｍｏ（Ｓ，Ｏ－Ｃ_６Ｈ_４－１，２］~－（Ｍ）［Ｍｏ_２（ＣＯ）_３（Ｓ，Ｏ－Ｃ_６Ｈ_４－１，２）_３］~（２－）（Ｄ），［Ｍｏ_３（ＣＯ）_７（Ｓ，Ｏ－Ｃ_６Ｈ_４－１，２）_３］~（２－）（Ｔ），和［Ｍｏ_２Ｆｅ（ＣＯ）_４（Ｓ，Ｏ－Ｃ_６Ｈ_４－１，２）_３Ｃｌ_２］~（２－）（Ｔ_ｆ）的合成化学与结构化学，并通过Ｘ－射线光电子能谱，红外光谱和电化学环伏安研究，深入探讨了它们的混合价，电子迁移和电化学行为，也讨论了有趣的Ｏ_３ＭｏＳ_３结构单元。
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| 关 键 词： | O_3MoS_3单元，Mo／Fe／S化合物，混合价，合成与结构化学，电化学行为 |
Investigation of the Mo-S, Mo-Fe-S Cluster Compounds Containing Mo-Microenvironment Structural Unit, O_3MoS_3, of Nitrogenase |
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| Zhuang Bo-Tao,Huang Liang-Ren, Lan An-Jian, He Ling-Jie,Pan Bing-Hua, Yu Pei-Hua.Investigation of the Mo-S, Mo-Fe-S Cluster Compounds Containing Mo-Microenvironment Structural Unit, O_3MoS_3, of Nitrogenase[J].Chinese Journal of Structural Chemistry,1995(3). |
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| Authors: | Zhuang Bo-Tao Huang Liang-Ren Lan An-Jian He Ling-Jie Pan Bing-Hua Yu Pei-Hua |
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| Abstract: | The synthetic and structural chemistry of four series of cluster compouds containing Mo-microenvironment structural unit, O_3MoS_3, of nitrogenase, Mo(S,O-C_6H_4-1,2]￣-(M) Mo_2(CO)_3(S,O-C_6H_4-1,2)_3]￣(2-)(D),Mo_3(CO)_7(S,O-C_6H_4-1,2)_3]￣(2-)(T), and Mo_2Fe(CO)_4(S,O-C_6H_4-1,2)_3Cl_2]￣(2-)(T_f) has been investigated systematically and the interesting O_3MoS_3 structural unit was discussed by comparing with the EXAFS data of FeMo-co of nitrogenase.Moreover, their mixed valence, charge transfer and electrochemical behavior were approached by the studies on their X-ray photoelectron spectra, infrared spectra and cyclic voltammetry. |
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| Keywords: | O_3MoS_3 unit Mo/Fe/S compound synthetic and structural chemistry mixed valence charge transfer electrochemical behavior |
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