| Synthesis and Crystal Structure of 2,3,4,6-Tetra-O-acetyl-1-{2-[(4-nitrophenoxy)methyl]-1,3,4-thiadiazole-5-thione-4-yl}-1-deoxy-β-D-glucopyranose |
| |
| 作者姓名： | WANG Zhi-Feng ZHAO Gui-Long TIAN Lai-Jin |
| |
| 作者单位： | WANG Zhi-Feng,TIAN Lai-Jin(School of Chemistry and Chemical Engineering,Qufu Normal University,Jining 273165,China);ZHAO Gui-Long(Tianjin Key Laboratory of Molecular Design and Drug Discovery,Tianjin Institute of Pharmaceutical Research,Tianjin 300193,China) |
| |
| 基金项目： | Supported by Scientific and Technological Support Plan by State MinislTy of Science and Technology （2007BAI40B01） |
| |
| 摘 要： | The title compound has been synthesized and its crystal structure was determined by single-crystal X-ray diffraction.The crystal is of orthorhombic system (C23H25N3O12S2,Mr=599.58),space group P212121 with a=6.2102(12),b=17.803(4),c=24.223(5),V=2678.0(9)3,Z=4,Dc=1.487 g/cm3,F(000)=1248,μ=0.268 mm-1,the final R=0.0483 and wR=0.1108 for 4174 observed reflections (I 2σ(I)).The C=S bond,which parallels to the anomeric C-H,adopts α orientation relative to the anomeric position of glucopyranoside.
|
| 关 键 词： | 晶体结构 葡萄糖 硝基苯氧基 合成 乙酰基 噻二唑 硫酮 脱氧 |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
