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Synthesis and Crystal Structure of a New Two-dimensional Manganese Coordination Polymer: [Mn(L)(1,4-bdc)]
引用本文:孔治国,马晓媛,徐占林,王秀艳.Synthesis and Crystal Structure of a New Two-dimensional Manganese Coordination Polymer: [Mn(L)(1,4-bdc)][J].结构化学,2011,30(7):927-930.
作者姓名:孔治国  马晓媛  徐占林  王秀艳
作者单位:Key Laboratory of Preparation and Applications of Environmental Friendly Materials;Jilin Normal University;Department of Chemistry;
基金项目:Supported by the Institute Foundation of Siping City (No.2009011)
摘    要:A new coordination polymer,Mn(L)(1,4-bdc)] (L=11-fluoro-dipyrido3,2-a:2,3-c]phenazine,1,4-bdc=benzene-1,4-dicarboxylate),has been synthesized through the hydrothermal method and characterized by elemental analysis,IR and single-crystal X-ray diffraction.It crystalli-zes in triclinic,space group P1 with a=9.7544(9),b=10.8254(10),c=11.5288(10),α=114.1300(10),β=96.6110(10),γ=105.0390(10)°,V=1038.62(16)3,Z=2,C 26 H 13 FMnN 4 O 4,M r=519.34,D c=1.661 g/cm 3,F(000)=526,μ(MoKa)=0.691 mm-1,R=0.0405 and wR=0.0977.The 1,4-bdc dianions link the neighboring Mn(II) atoms to yield a two-dimensional layer structure.The L ligands are attached on both sides of the layer.The π-π interactions between the L ligands of neighboring layers result in a three-dimensional supramolecular architecture.

关 键 词:锰配位聚合物  水热法合成  晶体结构  BDC  二维  超分子结构  元素分析  射线衍射

Synthesis and Crystal Structure of a New Two-dimensional Manganese Coordination Polymer:[Mn(L)(1,4-bdc)]
KONG Zhi-Guo,MA Xiao-Yuan,XU Zhan-Lin,WANG Xiu-Yan.Synthesis and Crystal Structure of a New Two-dimensional Manganese Coordination Polymer:[Mn(L)(1,4-bdc)][J].Chinese Journal of Structural Chemistry,2011,30(7):927-930.
Authors:KONG Zhi-Guo  MA Xiao-Yuan  XU Zhan-Lin  WANG Xiu-Yan
Institution:Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, China;Department of Chemistry,Jilin Normal University, Siping 136000, China
Abstract:A new coordination polymer, Mn(L)(1,4-bdc)] (L=11-fluoro-dipyrido3,2- a:2',3'-c]phenazine, 1,4-bdc=benzene-1,4-dicarboxylate),has been synthesized through the hydrothermal method and characterized by elemental analysis, IR and single-crystal X-ray diffraction. It crystalli-zes in triclinic, space group P1 with a=9.7544(9),b=10.8254(10),c=11.5288(10)A,α=114.1300(10),β=96.6110(10),γ=105.0390(10)°,V=1038.62(16)A<'3>,Z=2, C<,26>H<,13>FMnN<,4>O<,4>, Mr =519.34,D<,c>=1.661g/cm<'3>,F(000)=526,μ(MoKa)=0.691 mm<'-1>,R=0.0405 and wR=0.0977.The 1,4-bdc dianions link the neighboring Mn(Ⅱ)atoms to yield a two-dimensional layer structure.The L ligands are attached on both sides of the layer. The π-π interactions between the L ligands ofneighboring layers result in a three-dimensional supramolecular architecture.
Keywords:manganese complex  crystal structure  coordination polymer  11-fluoro-dipyrido[3  2-a:2  3-c]phenazine  
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