| Chiral Resolution of β-dl-Phenylalanine Using Chiral Macrocyclic Nickel(Ⅱ) Complexes |
| |
| 引用本文： | 欧光川,李治章,张敏,袁先友.Chiral Resolution of β-dl-Phenylalanine Using Chiral Macrocyclic Nickel(Ⅱ) Complexes[J].结构化学,2014,33(5):707-712. |
| |
| 作者姓名： | 欧光川 李治章 张敏 袁先友 |
| |
| 作者单位： | Department of Biology and Chemistry, Hunan University of Science and Engineering |
| |
| 基金项目： | Supported by the Scientific Research Fund of Hunan Provincial Education Department（13B029,13A030,13CY029）; the Program for Excellent Talents in Hunan University of Science and Engineering（2013）; the Construct Program of the Key Discipline in Hunan Province（2011-76）; the Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province（2012-318）; NSF of Hunan（11JJ2009） |
| |
| 摘 要： | The reactions of chiral four-coordinated nickel(Ⅱ) complex Ni(RR-L)](ClO4)2/Ni(SS- L)](ClO4)2 with β-dl-phenylalanine in acetonitrile/water gave a six-coordinated enantiomer of Ni(RR-L)(β-d-HPhe)](ClO4)2(1) and Ni(SS-L)(β-l-HPhe)](ClO4)2(2), respectively(L = 5,5,7, 12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, HPhe = phenylalanine). Single-crystal X-ray diffraction analyses revealed that the nickel(Ⅱ) atom displays a distorted octahedral coordination geometry by coordinating with four nitrogen atoms of L in a folded configuration, and two carboxylate oxygen atoms of β-d/l-HPhe in cis-position in both complexes. The monomers of Ni(RR-L)(β-d-HPhe)]2+ and Ni(SS-L)(β-l-HPhe)]2+ are connected through intermolecular hydrogen bonds to generate one-dimensional zigzag chains, respectively. The homochiral natures of 1 and 2 are confirmed by the results of CD spectroscopy.
|
| 关 键 词： | chiral resolution macrocyclic nickel(Ⅱ) complexes β-dl-phenylalanine |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
