| Synthesis and Crystal Structure of aNovel Polymer Copper（ Ⅱ） Complex |
| |
| 引用本文： | 王军,卑凤利,李人宇,杨绪杰,陆路德,汪信.Synthesis and Crystal Structure of aNovel Polymer Copper（ Ⅱ） Complex[J].结构化学,2003,22(6):665-668. |
| |
| 作者姓名： | 王军 卑凤利 李人宇 杨绪杰 陆路德 汪信 |
| |
| 作者单位： | WANG Juna，b BEI Feng-Lia LI Ren-Yua YANG Xu-Jiea LU Lu-Dea WANG Xina① a (Materials Chemistry Laboratory，Nanjing University of Science & Technology，Nanjing 210094，China) b(Department of Police Technique，Jiangsu Police Institute，Nanjing 210012，China) |
| |
| 摘 要： | 1 INTRODUCTION One-dimensional coordination polymers of metal complexes have been extensively studied for many years owing to their unusual properties, and many efforts have been made to prepare these kinds of complexes. Study on these polymer complexes has an active field of coordination chemistry in recent years1～5]. In this study we obtained a com- plex C14H9CuNO3CH3OH, of which the carboxy- late oxygen atom acts as the bridging ligands to coordinate to the second metal atom, fo…
|
| 关 键 词： | salicylaldehyde o-aminobenzoic acid crystal structure one-dimensional chain N-salicylidene-2-amino-phenylacidato copper(Ⅱ) |
Synthesis and Crystal Structure of a Novel Polymer Copper(Ⅱ) Complex |
| |
| Abstract: | A novel chain complex was synthesized and its crystal structure has been deter- mined by X-ray diffraction technique. It was found that the local coordination geometry around Cu(Ⅱ) is a distorted tetrahedron and C14H9CuNO3@CH3OH is bridged by the carboxylate oxygen atom to form an infinite one-dimensional linear chain. The hydrogen bond exists between O(1) and solvate molecule O(4). The crystal belongs to monoclinic, space group P21 with a = 9.6650(19), b = 7.1280(14), c = 9.925(2)(A°),β= 98.39(3)°, V = 676.4(2)(A°)3, Z = 2, F(000) = 342 and μ(MoKα) = 1.629 mm-1 . |
| |
| Keywords: | salicylaldehyde o-aminobenzoic acid crystal structure one-dimensional chain |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
