| Synthesis, Crystal Structure and Luminescent Properties of [Zn（bipy）_2（H_2O）_4]·L·3H_2O |
| |
| 引用本文： | 陈友存,沈菲,王彦,许军军,汪快兵.Synthesis, Crystal Structure and Luminescent Properties of [Zn（bipy）_2（H_2O）_4]·L·3H_2O[J].结构化学,2011,30(9):1251-1256. |
| |
| 作者姓名： | 陈友存 沈菲 王彦 许军军 汪快兵 |
| |
| 作者单位： | Anhui Provincial Laboratory of Optoelectronic and Magnetism Functional Materials;School of Chemistry and Chemical Engineering;Anqing Normal University;State Key Laboratory of Coordination Chemistry;Nanjing University; |
| |
| 基金项目： | Supported by the National Natural Science Foundation of China (Nos. 20771006 and 20901004) |
| |
| 摘 要： | A novel coordination complex Zn(bipy)2(H2O)4]·L·3H2O (1, bipy = 4,4'-bipyridine, LHNa = aniline-2,5-disulfonic acid monosodium salt) has been synthesized from LHNa by using hydrothermal method and structurally characterized. The result indicates that complex 1 belongs to the monoclinic system, space group P21/c with a = 20.392(3), b = 7.4052(12), c = 23.843(3) , β = 116.253(10)°, V = 3.2291(8) 3, Z = 4, Dc = 1.553 g·cm-3, μ = 0.962 mm-1, F(000) = 1568, and the final R = 0.0497 and wR = 0.1290. The complex 1 has a 0-D discrete structure, and generates an infinite 3-D network with the aid of O–H…O hydrogen bonds and π-π interactions.
|
| 关 键 词： | 晶体结构 发光性能 合成 联吡啶 单斜晶系 离散结构 相互作用 H2O |
Synthesis, Crystal Structure and Luminescent Properties of [Zn（bipy）_2（H_2O）_4]·L·3H_2O |
| |
| CHEN You-Cun
,
SHEN Fei
,
WANG Yan
,
XU Jun-Jun
,
WANG Kuai-Bing.Synthesis, Crystal Structure and Luminescent Properties of [Zn（bipy）_2（H_2O）_4]·L·3H_2O[J].Chinese Journal of Structural Chemistry,2011,30(9):1251-1256. |
| |
| Authors: | CHEN You-Cun SHEN Fei WANG Yan XU Jun-Jun WANG Kuai-Bing |
| |
| Institution: | 1. Anhui Provincial Laboratory of Optoelectronic and Magnetism Functional Materials, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, China
2. Anhui Provincial Laboratory of Optoelectronic and Magnetism Functional Materials, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, China／State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China |
| |
| Abstract: | A novel coordination complex Zn(bipy)2(H2O)4]·L·3H2O (1, bipy = 4,4'-bipyridine, LHNa = aniline-2,5-disulfonic acid monosodium salt) has been synthesized from LHNa by using hydrothermal method and structurally characterized. The result indicates that complex 1 belongs to the monoclinic system, space group P21/c with a = 20.392(3), b = 7.4052(12), c = 23.843(3) , β = 116.253(10)°, V = 3.2291(8) 3, Z = 4, Dc = 1.553 g·cm-3, μ = 0.962 mm-1, F(000) = 1568, and the final R = 0.0497 and wR = 0.1290. The complex 1 has a 0-D discrete structure, and generates an infinite 3-D network with the aid of O–H…O hydrogen bonds and π-π interactions. |
| |
| Keywords: | zinc（Ⅱ） complex crystal structure π-π interactions hydrogen bonds |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
