| Synthesis and Crystal Structure of a Novel 1D Mercury（II） Iodide Coordination Polymer Containing 40-Membered Macrocycle |
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| 引用本文： | 甘小平,孔林,吴鹏,吕晨,涂雨龙,陈怡欣,周虹屏,吴杰颖,田玉鹏.Synthesis and Crystal Structure of a Novel 1D Mercury（II） Iodide Coordination Polymer Containing 40-Membered Macrocycle[J].结构化学,2011,30(11):1650-1655. |
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| 作者姓名： | 甘小平 孔林 吴鹏 吕晨 涂雨龙 陈怡欣 周虹屏 吴杰颖 田玉鹏 |
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| 作者单位： | Department of Applied Chemistry;School of Science;Anhui Agricultural University;School of Chemistry and Chemical Engineering;Anhui University and Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province; |
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| 基金项目： | supported by the National Natural Science Foundation of China (21071001, 50873001); Education Committee of Anhui Province (KJ2009A52, KJ2010A030); the Team for Scientific Innovation Foundation of Anhui Province (2006KJ007TD); Science and Technological Fund of Anhui Province for Outstanding Youth (10040606Y22); the 211 Project of Anhui University, Ministry of Education Funded Projects Focus on Returned Overseas Scholar; the Youth Foundation of Anhui Agricultural University (2009ZR25) |
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| 摘 要： | A mercury coordination polymer Hg3(TizT)2I6]n (Mr = 1921.72, TizT = 2,4,6- tri(imidazole-1-yl)-1,3,5-triazine) containing a 40-membered macrocycle which was constructed by four TizT ligands and four mercury(II) iodide molecules had been synthesized by the reaction of HgI2 with TizT. The complex was characterized by elemental analysis, FT-IR, 1H NMR spectra and X-ray crystallography. The crystal of the complex belongs to the monoclinic system and C2/c space group with a = 35.840(5), b = 8.169(5), c = 14.980(5) , β = 104.466(5)°, Z = 4, V = 4247(3) 3, Dc = 3.006 g·cm-3, μ = 15.223 mm-1, F(000) = 3384, Rint = 0.0504, wR = 0.0833 and constructs a chair-like conformation of cyclohexane one by one, which forms a 1-D polymer through the fashion of fused ring aromatic hydrocarbon. The hydrogen bonds and π-π interactions shape the 2-D network structure. The two compounds excited weak fluorescence.
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| 关 键 词： | 配位聚合物 一维聚合物 晶体结构 碘化汞 合成 X射线晶体学 分子构造 元素分析 |
Synthesis and Crystal Structure of a Novel 1D Mercury(II) Iodide Coordination Polymer Containing 40-Membered Macrocycle |
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| GAN Xiao-Ping
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KONG Ling
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WU Peng
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LV Chen
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TU Yu-Long
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CHEN Yi-Xin
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ZHOU Hong-Ping
,
WU Jie-Ying
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TIAN Yu-Peng.Synthesis and Crystal Structure of a Novel 1D Mercury(II) Iodide Coordination Polymer Containing 40-Membered Macrocycle[J].Chinese Journal of Structural Chemistry,2011,30(11):1650-1655. |
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| Authors: | GAN Xiao-Ping KONG Ling WU Peng LV Chen TU Yu-Long CHEN Yi-Xin ZHOU Hong-Ping WU Jie-Ying TIAN Yu-Peng |
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| Institution: | 1. School of Chemistry and Chemical Engineering, Anhui University andKey Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Hefei 230039, China／Department of Applied Chemistry, School of Science, Anhui Agricultural University, Hefei 230036, China
2. School of Chemistry and Chemical Engineering, Anhui University andKey Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Hefei 230039, China |
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| Abstract: | A mercury coordination polymer Hg3(TizT)2I6]n (Mr = 1921.72, TizT = 2,4,6- tri(imidazole-1-yl)-1,3,5-triazine) containing a 40-membered macrocycle which was constructed by four TizT ligands and four mercury(II) iodide molecules had been synthesized by the reaction of HgI2 with TizT. The complex was characterized by elemental analysis, FT-IR, 1H NMR spectra and X-ray crystallography. The crystal of the complex belongs to the monoclinic system and C2/c space group with a = 35.840(5), b = 8.169(5), c = 14.980... |
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| Keywords: | macrocycle crystal structure photoluminescence |
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