| Solvothermal Synthesis and Crystal Structure of a Zn（II） Microporous Metal-organic Framework |
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| 作者姓名： | LI Dong-Ping LI Jing LI Xu CHEN Ping-Hua JIAO Xiao-Yan LI Yong-Xiu |
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| 作者单位： | [1]Department of Chemistry, Nanchang University, Nanchang 330031, China [2]Department of Biology and Chemistry, College of Science and Technology, Nanchang University, Nanchang 330029, China |
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| 基金项目： | Supported by the Natural Science Foundation of Jiangxi Province （20114BAB213001 ） and the Education Department of Jiangxi Province （GJJ 12041 ） |
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| 摘 要： | A novel three-dimensional Zn(Ⅱ) coordination polymer, Zn3(C2H2N3)4(SiF6), has been synthesized under solvothermal conditions using 1H-1,2,4-triazole-3-carboxylic acid and zinc fluoride as the starting materials. The complex has been characterized by elemental analysis, IR, TG analysis and single-crystal X-ray diffraction analysis. The complex crystallizes in the tetragonal I4/mmm space group with a=11.592(0), c=7.526(1), V=1011.3(2)3 , Z=2, Mr=610.46, Dc=2.005 g/cm3 and F(000)=596. The final R=0.0312 and wR=0.067 for 319 observed reflections with I>2σ(I). In the title complex, the Zn centers are interconnected by μ 3 -bridging triazole ligands to form a microporous three-dimensional metal-organic framework.
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| 关 键 词： | solvothermal synthesis Zn(Ⅱ) microporous metal-organic framework |
Solvothermal Synthesis and Crystal Structure of a Zn(II) Microporous Metal-organic Framework |
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| LI Dong-Ping,LI Jing,LI Xu,CHEN Ping-Hua,JIAO Xiao-Yan,LI Yong-Xiu.Solvothermal Synthesis and Crystal Structure of a Zn(II) Microporous Metal-organic Framework[J].Chinese Journal of Structural Chemistry,2012,31(11):1676-1680. |
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| Authors: | LI Dong-Ping a LI Jing a LI Xu b CHEN Ping-Hua a JIAO Xiao-Yan a LI Yong-Xiu |
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| Institution: | 1. Department of Chemistry, Nanchang University, Nanchang 330031, China
2. Department of Biology and Chemistry, College of Science and Technology, Nanchang University, Nanchang 330029, China |
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| Abstract: | A novel three-dimensional Zn(Ⅱ) coordination polymer, Zn3(C2H2N3)4(SiF6), has been synthesized under solvothermal conditions using 1H-1,2,4-triazole-3-carboxylic acid and zinc fluoride as the starting materials. The complex has been characterized by elemental analysis, IR, TG analysis and single-crystal X-ray diffraction analysis. The complex crystallizes in the tetragonal I4/mmm space group with a=11.592(0), c=7.526(1), V=1011.3(2)3 , Z=2, Mr=610.46, Dc=2.005 g/cm3 and F(000)=596. The final R=0.0312 and wR=0.067 for 319 observed reflections with I>2σ(I). In the title complex, the Zn centers are interconnected by μ 3 -bridging triazole ligands to form a microporous three-dimensional metal-organic framework. |
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| Keywords: | solvothermal synthesis Zn(II) microporous metal-organic framework |
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