| Synthesis and Crystal Structure of a One-dimensional Mn（Ⅱ） Coordination Polymer with 1,3-bis（4-pyridyl）propane |
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| 引用本文： | 周燕,韩磊,潘建国,李星.Synthesis and Crystal Structure of a One-dimensional Mn（Ⅱ） Coordination Polymer with 1,3-bis（4-pyridyl）propane[J].结构化学,2009,28(3):348-352. |
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| 作者姓名： | 周燕 韩磊 潘建国 李星 |
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| 作者单位： | State Key Laboratory Base of Novel Functional Materials & Preparation Science, Faculty of Materials Science & Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China
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| 基金项目： | 国家自然科学基金，宁波市自然科学基金，the K. C. Wong Magna Fund in Ningbo University |
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| 摘 要： | A new 1D zigzag chain coordination polymer, { Mn（bpp）（bac）2]·（CHaCN）}n 1 （bpp = 1,3-bis（4-pyridyl）propane, Hbac = benzoylacetone）, has been synthesized and characterized by FT-IR spectroscopy, thermal analysis and X-ray single-crystal diffraction. In the molecular structure, all Mn atoms locate in an octahedral geometry. The guest CH3CN molecules are included in the 1D channels of the 3D packing structure of 1. Crystal data： C35H35MnNaO4, Mr = 616.60, monoclinic, space group P211c, a = 17.691（4）, b = 18,955（4）, c = 9.712（6） A, β = 93.91（3）°, V = 3249.31（1） A^3, Z = 4, Dc = 1.260 g/cm^3, F（000） = 1292, 20max = 54.9°, μ = 0.447 mm^-1, the final S = 1.020, R = 0.0693 and wR = 0.1497.
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| 关 键 词： | 配位聚合物 吡啶基 晶体结构 一维 合成 丙烷 锰 分子结构 |
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