| Synthesis and Crystal Structure of a Dialkyltin Benzamidoacetate Compound {[n-Bu2Sn（O2CCH2NHCOC6H5）]2O}2·C6H6 |
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| 引用本文： | 张复兴,王剑秋,邝代治,冯泳兰,许志锋,陈志敏,曾荣英.Synthesis and Crystal Structure of a Dialkyltin Benzamidoacetate Compound {[n-Bu2Sn（O2CCH2NHCOC6H5）]2O}2·C6H6[J].结构化学,2009,28(4):482-486. |
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| 作者姓名： | 张复兴 王剑秋 邝代治 冯泳兰 许志锋 陈志敏 曾荣英 |
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| 作者单位： | Department of Chemistry and Material Science,Hunan Key Laboratory of Functional Organometallic Materials Hengyang Normal University,Hengyang,Hunan 421008,China
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| 基金项目： | the Science and Technology Fund of Hunan Province，the Key Fund of Educalion Committee of Hunan Province，the Construct Program of the Key Discipline in Hunan Province |
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| 摘 要： | A dialkyltin benzamidoacetate compound {n-Bu2Sn（O2CCH2NHCOC6H5）]2O}2· C6H6 has been synthesized by the reaction of dialkyltin oxide with benzamidoacetic acid in 1：1 molar ratio, and its structure was determined by X-ray single-crystal diffraction. The crystal belongs to orthorhombic, space group Pca21, with a = 1.9134（4）, b = 1.9605（4）, c = 2.0657（4） nm, Z = 4, V = 7.749（3） nm^3, Dc = 1.054 mg·m^-3,μ（MoKa） = 1.337 mm^-1, F（000） = 3576, the final R = 0.0405 and wR = 0.0860. According to the structural analysis, the tin atom adopts a distorted five-coordinate trigonal bipyramidal geometry, and the dimer structure is shaped by one planar four-membered Sn2O2 ring.
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| 关 键 词： | 晶体结构 化合物 合成 A型 苯 氧化反应 单晶衍射 偏差因子 |
Synthesis and Crystal Structure of a Dialkyltin Benzamidoacetate Compound {[n-Bu2Sn(O2CCH2NHCOC6H5)]2O)2·C6H6 |
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| ZHANG Fu-Xing,WANG Jian-Qiu,KUANG Dai-Zhi,FENG Yong-Lan,XU Zhi-Feng,CHEN Zhi-Min,ZENG Rong-Ying.Synthesis and Crystal Structure of a Dialkyltin Benzamidoacetate Compound {[n-Bu2Sn(O2CCH2NHCOC6H5)]2O)2·C6H6[J].Chinese Journal of Structural Chemistry,2009,28(4):482-486. |
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| Authors: | ZHANG Fu-Xing WANG Jian-Qiu KUANG Dai-Zhi FENG Yong-Lan XU Zhi-Feng CHEN Zhi-Min ZENG Rong-Ying |
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| Institution: | Department of Chemistry and Material Science,Hunan Key Laboratory of Functional Organometallic Materials Hengyang Normal University,Hengyang,Hunan 421008,China |
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| Abstract: | A dialkyltin benzamidoacetate compound {n-Bu2Sn(O2CCH2NHCOC6H5)]2O}2·C6H6 has been synthesized by the reaction of dialkyltin oxide with benzamidoacetic acid in 1:1 molar ratio,and its structurle was determined by X-ray single-crystal diffraction.The crystal belongs to orthorhombic,space group Pca21,with a=1.9134(4),b=1.9605(4),c=2.0657(4)nm,Z=4,V=7.749(3)nm3,Dc=1.054 mg·m-3,μ(MoKa)=1.337 mm-1,F(000)=3576,the final R=0.0405 and wR=0.0860.According to the structural analysis,the tin atom adopts a distorted five-coordinate trigonal bipyramidal geometry,and the dimer structure is shaped by one planar four-membered Sn2O2 ring. |
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| Keywords: | diaikyltin organotin benzamidoacetic acid synthesis crystal structure |
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