| Synthesis and Crystal Structure of a Novel One-dimensional Coordination Polymer [ （C14H18N2）（Pb2i6）]n |
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| 引用本文： | 黄长沧,李浩宏,陈之荣,陈家鸿,任永刚,倪朝霞.Synthesis and Crystal Structure of a Novel One-dimensional Coordination Polymer [ （C14H18N2）（Pb2i6）]n[J].结构化学,2004,23(9):1013-1016. |
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| 作者姓名： | 黄长沧 李浩宏 陈之荣 陈家鸿 任永刚 倪朝霞 |
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| 作者单位： | Department of Chemistry，Fuzhou University，Fuzhou，Fujian 350002，China |
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| 基金项目： | This work was supported by the Foundation of Education Committee of Fujian Province (JB01020) |
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| 摘 要： | 1 INTRODUCTION The organic-inorganic hybrid material is a new type of composite between organic and inorganic polymers, and has captured the imaginations of che- mists due to its potential applications in electric con- ductivity, magnetism, ion exchange…
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| 关 键 词： | 合成 晶体结构 配位聚合物 铅配合物 碘化物 四元铵 |
Synthesis and Crystal Structure of a Novel Onedimensional Coordination Polymer[(C14H18N2)(Pb2I6)]n |
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| Institution: | Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China;Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China;Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China;Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China;Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China;Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China |
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| Abstract: | The organic-inorganic hybrid (C14H18N2)(Pb2I6)]n (C14H18N2]2+ = N,N?-1,4-buthy- lenedipyridinium (BDP)) with one-dimensional structure was self-assembling synthesized by the organic quaternary ammonium template. It crystallizes in monoclinic, space group P21/n with a = 8.2596(9), b = 15.1363(19), c = 11.1603(13) , b = 97.915(5)o, C14H18N2Pb2I6, Mr = 1390.10, V = 1382.0(3) 3, Z = 2, Dc = 3.341 g/cm3, m(MoKa) = 18.870 mm-1, F(000) = 1196, the final R = 0.0420 and wR = 0.0921 for 2156 observed reflections with I > 2s(I). The title compound consists of cations (C14H18N2]2+ ) and anion chain (Pb2I62]n) which are combined by static attractive forces in the crystal. |
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| Keywords: | coordination polymers template synthesis iodide quaternary ammonium |
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