| Synthesis and Crystal Structure of a New Complex {[Co~(Ⅲ)L_2]·[Co~(Ⅱ)(H_2O)_6]_(0.5)·2.25H_2O}_4 (H_2L = N-(2-Hydroxyphenyl)salicylidenimine) |
| |
| 引用本文： | 杨丽丽,党振华,徐立.Synthesis and Crystal Structure of a New Complex {[Co~(Ⅲ)L_2]·[Co~(Ⅱ)(H_2O)_6]_(0.5)·2.25H_2O}_4 (H_2L = N-(2-Hydroxyphenyl)salicylidenimine)[J].结构化学,2009,28(4). |
| |
| 作者姓名： | 杨丽丽 党振华 徐立 |
| |
| 作者单位： | YANG Li-Li,DANG Zhen-Hua(State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China;Graduate School of the Chinese Academy of Sciences,Beijing 100039,China);XU Li(State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China)
|
| |
| 摘 要： | The reaction of Co(OAc)2·4H2O with the Schiff base H2L in a methanol solution affords the red crystals of {CoIIIL2]·CoII(H2O)6]0.5·2.25H2O}4 1 (H2L = N-(2-hydroxyphenyl) sali-cylidenimine). The molecular and crystal structures were determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/n, C104H114Co6N8O37, Mr = 2421.61, a = 10.625(3), b = 16.335(4), c = 15.265(4) , β = 102.990(4)o, V = 2581.6(11) 3, Z = 1, Dc = 1.558 g/cm3, μ = 1.034 mm-1, F(000) = 1252, R = 0.0414 and wR = 0.1167 for 5889 reflections. The Co(III) atom is six-coordinated by two nitrogen atoms and four oxygen atoms of two tridentate L ligands. The abundant hydrogen bonding interactions extend the complex into a one-dimensional supra-molecular framework. The uncoordinated water molecules act as space-fillers and consolidate the whole architecture through the hydrogen bonding interactions.
|
Synthesis and Crystal Structure of a New Complex {[CoⅢL2]·[CoⅡ(H2O)6]0.5·2.25H2O}4 (H2L=N-(2-Hydroxyphenyl)salicylidenimine) |
| |
| YANG Li-Li,DANG Zhen-Hua,XU Li.Synthesis and Crystal Structure of a New Complex {[CoⅢL2]·[CoⅡ(H2O)6]0.5·2.25H2O}4 (H2L=N-(2-Hydroxyphenyl)salicylidenimine)[J].Chinese Journal of Structural Chemistry,2009,28(4). |
| |
| Authors: | YANG Li-Li DANG Zhen-Hua XU Li |
| |
| Abstract: | The reaction of Co(OAc)2·4H2O with the Schiff base H2L in a methanol solution affords the red crystals of {CoⅢL2]·CoⅡ(H2O)6]0.5·2.25H2O}4 1(H2L=N-(2-hydroxyphenyl) salicylidenimine).The molecular and crystal structures were determined by single-crystal X-ray diffraction.The crystal is of monoclinic,space group P21/n,C104H114Co6N8O37,Mr=2421.61,a=
10.625(3),b=16.335(4),c=15.265(4)(A),β=102.990(4)°,V=2581.6(11)(A)3,Z=1,Dc=1.558 g/cm3,μ=1.034 mm-1,F(000)=1252,R=0.0414 and wR=0.1167 for 5889 reflections.The Co(Ⅲ)atom is six-coordinated by two nitrogen atoms and four oxygen atoms of two tridentate L
ligands.The abundant hydrogen bonding interactions extend the complex into a one-dimensional supra- molecular framework.The uncoordinated water molecules act as space-fillers and consolidate the whole architecture through the hydrogen bonding interactions. |
| |
| Keywords: | Schiff base N-(2-hydroxyphenyl)salicylidenimine crystal structure |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
