| Synthesis and Crystal Structure of a Dinuclear Compound Cu2[（O=PPh2）2N]2（μ-O2PPh2）2 |
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| 引用本文： | 王欣,项生昌,盛天录,傅瑞标,李亚敏,吴新涛.Synthesis and Crystal Structure of a Dinuclear Compound Cu2[（O=PPh2）2N]2（μ-O2PPh2）2[J].结构化学,2006,25(4):459-464. |
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| 作者姓名： | 王欣 项生昌 盛天录 傅瑞标 李亚敏 吴新涛 |
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| 作者单位： | State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China，State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China |
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| 基金项目： | This research was supported by the grants from the State Key Laboratory of Structural Chemistry, the National Science and Technology of China (001CB1089), the Chinese Academy of Sciences (CAS), the National Natural Science Foundation of China (20273073, 20333070, 90206040) and the NaturalScience Foundation of CAS and Fujian Province (2004HZ01-1, 2004J041, 2003J042) |
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| 摘 要： | 1 INTRODUCTION Transition-metal complexes supported by poly-dentate phosphine ligands have been widely studieddue to the unique photophysical properties andpotential applications as industrial catalysts, mole-cular sensors and drugs1~3]. As known, oxidation ofphosphine ligands could happen in the synthesisreaction to result in novel complex with unexpectedstructure4, 5]. For example, the structure of complexFe((OPPh2)2N)36] is an octahedral tris-chelate arrange-ment of the oxidized a…
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| 关 键 词： | 合成 晶体结构 双核化合物 铜（Ⅱ）配合物 氧化 水解 |
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