| Crystal and Molecular Structure of a New Mono－substituted Titanocene Complex，｛（η~5－Cp）［η~5－（1－（4－OCH_3）C_6H_4）C_6H_（10）Cp］（TiCl_2）｝·0．3（n－C_6H_（14）） |
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| 作者姓名： | Tian Jun Hu Ning-Hai Sheng Qi Huang Bao-Tong |
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| 作者单位： | Changchun Institute of Applied Chemistry，Chinese Academy of Sciences，Changchun 130022 |
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| 摘 要： | ＣｒｙｓｔａｌａｎｄＭｏｌｅｃｕｌａｒＳｔｒｕｃｔｕｒｅｏｆａＮｅｗＭｏｎｏ－ｓｕｂｓｔｉｔｕｔｅｄＴｉｔａｎｏｃｅｎｅＣｏｍｐｌｅｘ，｛（η~５－Ｃｐ）［η~５－（１－（４－ＯＣＨ_３）Ｃ_６Ｈ_４）Ｃ_６Ｈ_（１０）Ｃｐ］（ＴｉＣｌ_２）｝·０．３（ｎ－...
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Crystal and Molecular Structure of a New Mono-substituted Titanocene Complex, {(η￣5-Cp) [η￣5-(1-(4-OCH_3) C_6H_4) C_6H_(10)Cp] (TiCl_2)} ·0.3 (n-C_6H_(14)) |
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| Tian Jun,Hu Ning-Hai, Sheng Qi, Huang Bao-Tong.Crystal and Molecular Structure of a New Mono-substituted Titanocene Complex, {(η￣5-Cp) [η￣5-(1-(4-OCH_3) C_6H_4) C_6H_(10)Cp] (TiCl_2)} ·0.3 (n-C_6H_(14))[J].Chinese Journal of Structural Chemistry,1995(2). |
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| Authors: | Tian Jun Hu Ning-Hai Sheng Qi Huang Bao-Tong |
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| Abstract: | ?-Cyclopentadienyl)η￣5- (1-(4-methoxyphenyl)cyclohexyl)-cyclopentadienyl]titanium dichloride has been synthesized through a novel modified reaction route. The molecular structure of the title complex was determined by single-crystal Xray diffraction. Crystallographic data: C_(23)H_(26)OCl_2Ti· 0. 3C_6H_(14),M_r=462. 44, triclinic, P1, a=11. 704(2) , b= 16. 340(4) , C=6. 824(1), a=90. 51(2) , β= 106. 98(1), γ=69. 82(2)°, V= 1165. 4(4) , Z=2, D_c= 1. 317 g/cm￣3, μ(MoKa) = 6. 2cm￣(-1), F(000) = 486 , and the final R= 0. 059 and R_w= 0. 085 for 2723 observed reflections with I>3σ(I). The cyclopentadienyl ring is symmetrically bonded to Ti(Ti-C distances 2. 361 (5)～2. 386 (5)) but the substituted cyclopentadienyl ring is asymmetrically bonded (Ti C2. 327 (4)～2. 438 (4)). The solvent petroleum-ether is disordered in the crystal. |
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| Keywords: | crystal structure mono-substituted titanocene complex metallocene Derivative |
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