| 金刚烷胺硝酸盐的晶体结构 |
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| 引用本文： | 赵国良,冯云龙,胡晓春,孔黎春.金刚烷胺硝酸盐的晶体结构[J].结构化学,2003,22(3):321-323. |
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| 作者姓名： | 赵国良 冯云龙 胡晓春 孔黎春 |
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| 作者单位： | 浙江师范大学物理化学研究所,浙江师范大学化学系,金华,231004 |
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| 基金项目： | 浙江省科技厅基金资助项目(编号: 012061) |
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| 摘 要： | 报道了金刚烷胺硝酸盐(三环3,3,1,11,7]癸烷-1-胺硝酸盐,C10H18N2O3,Mr = 214.26)的晶体结构。该晶体属于正交晶系,空间群为P212121, 晶胞参数:a = 6.380(1),b = 7.349(2),c = 22.801(5) ,V = 1069.0(4) 3,m(MoKa) = 0.098 mm-1,Z = 4,F(000) = 464,Dc =1.331 g/cm3。对于1172 (I ≥2s(I))个可观察衍射点,最终偏离因子R = 0.0310,wR = 0.0757。该晶体由金刚烷铵阳离子和硝酸根阴离子组成,金刚烷基为由椅式构象组成的一个稳定的三环结构。由于氢键作用,晶体呈二维平面无限结构。
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| 关 键 词： | 金刚烷胺 晶体结构 氢键 流感病毒 |
Crystal Structure of Adamantaneamine Nitrate |
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| ZHAO Guo-Liang,FENG Yun-Long,HU Xiao-Chun,KONG Li-Chun.Crystal Structure of Adamantaneamine Nitrate[J].Chinese Journal of Structural Chemistry,2003,22(3):321-323. |
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| Authors: | ZHAO Guo-Liang FENG Yun-Long HU Xiao-Chun KONG Li-Chun |
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| Abstract: | The crystal structure of adamantaneamine nitrate (tricyclo3,3,1,13,7]decane-1-amine nitrate, C10H18N2O3, Mr = 214.26) was determined by X-ray diffraction. The crystal belongs to the orthorhombic system, space group P212121 with a = 6.380(1), b = 7.349(2), c = 22.801(5) , V = 1069.0(4) 3, m(MoKa) = 0.098 mm-1, Z = 4, F(000) = 464 and Dc =1.331 g/cm3. The structure was refined to R = 0.0310 and wR = 0.0757 for 1172 observed reflections with I≥2s(I). The structure of the title compound consists of one adamantane ammonium and one nitrate, which are bridged by hydrogen bonds to form a two-dimensional infinite structure. |
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| Keywords: | adamantaneamine crystal structure hydrogen bond influenza virus |
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