| A 2D Lanthanide-organic Framework Based on Inorganic Lanthanum（Ⅲ） Sulfate Skeletons：Synthesis,Structure,and Luminescence and Thermal Properties |
| |
| 引用本文： | 冯勋,张改,张荣兰,孙倩倩,赵建社.A 2D Lanthanide-organic Framework Based on Inorganic Lanthanum（Ⅲ） Sulfate Skeletons：Synthesis,Structure,and Luminescence and Thermal Properties[J].结构化学,2011,30(1):144-150. |
| |
| 作者姓名： | 冯勋 张改 张荣兰 孙倩倩 赵建社 |
| |
| 作者单位： | Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education;College of Chemistry and Materials;Northwest University;College of Chemistry and Chemical Engineering;Luoyang Normal University; |
| |
| 基金项目： | supported by the National Natural Science Foundation of China (No.20971104); the Ph. D. Programs Foundation of Ministry of Education of China (No.200806970008); the Foundation of Education Committee of Henan Province (No.2010A150016); the Tackle Key Problem of Science and Technology Project of Henan Province (No.102102210450) |
| |
| 摘 要： | A new lanthanum coordination polymer formulated as {La2(pyda) 2(μ4-SO4) ·5H2O]· 2H2O}n(1,H2pyda = 2,6-pyridine-dicarboxylic acid) has been synthesized from the reaction of H2pyda with lanthanide nitrate in the presence of sulfate as a counter anion. The compound was characterized by elemental analysis,IR spectroscopy and X-ray single-crystal diffraction. It crystallizes in the orthorhombic system,space group Pna21,with a = 18.8558(19) ,b = 6.5831(7) and c = 18.7543(19) . The compound is a 2D hybrid,in which the La(Ⅲ) ions were doubly connected by the carboxylic group of pyda2-ligand to form the La(Ⅲ) dimer followed by being grafted into 1D zig-zag chains which are further connected into a 2D network containing {La(SO4) ]+}n helical chains. The interchain hydrogen bonding and π-π stacking interactions extended the 2D networks into a 3D supramolecular edifice.
|
| 关 键 词： | 二维网络 硫酸镧 有机无机 发光性能 稀土 合成 硫酸根离子 骨架 |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
