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Gas chromatographic analysis of xylidine isomers on heteroaromatic compounds
Authors:A Ono
Institution:(1) Chemical Laboratory, Takada Branch, Faculty of Education, Niigata University, Nishishiro-cho, 943 Joetsu-shi, Japan;(2) Present address: Department of Chemistry, Faculty of Education, Niigata University, 950-21 Niigata, Japan
Abstract:Summary Nicotinic acid, picolinic acid, isonicotinic acid, histidine and other amphoteric heteroaromatic compounds, uracil, thymine, isatin and other heteroaromatic compounds having imino and carbonyl groups as well as IH-benzotriazole, benzoguanamine and guanidine phosphate effectively resolved all the xylidine (dimethylaniline) isomers. Furthermore, the mixed phases of nicotinamide + p-amino-benzoic acid and melamine+barbituric acid also provided an appreciable resolution. These analyses were carried out using a support which were not treated with an alkali.
Keywords:Gas-liquid chromatography  Amphoteric heteroaromatic compounds as liquid phase  Analysis of xylidine isomers
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