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Glass capillary gas chromatography of C1?C4 mononitroalkanes. Pre-calculation of the relative retention
Authors:N Dimov  S Boneva
Institution:(1) Chemical-Pharmaceutical Research Institute, 1156 Sofia, Bulgaria;(2) Heavy-Chemical Technological Institute, 8010 Burgas, Bulgaria
Abstract:Summary The separation of C1–C4 mononitroalkanes on four wall-coated glass open tubular (capillary) columns (liquid phases: OV-101, Ucon-LB-550X, NPGS and Carbowax 20M) was investigated. Retention indices were determined and the influence of the different factors (analysis temperature, method of determining the gas holdup time and the nature of the stationary phases) on their reproducibility were studied. Linear regression equations permit the pre-calculation of the retention indices of C1–C4 mononitroalkanes from their properties on all liquid phases studied.
Keywords:Glass capillary GC  Separation  Mononitroalkanes  Retention index  Pre-calculation
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