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Problems related to the optimum separation conditions in liquid adsorption chromatography
Authors:J K Różyło  B Ościk-Mendyk
Institution:(1) Institute of Chemistry, M. Curie-Skłodowska University, 20-031 Lublin, Poland
Abstract:Summary Relationships derived from the thermodynamic formulation of TLC with a binary mobile phase are discussed. The adsorption equilibrium constant is determined from the linear form of a basic equation considering the adsorption process. This linear relationship is examined with help of TLC data obtained by using six different chromatographic systems. The adsorption equilibrium constant obtained from the TLC data is compared to the equilibrium constant determined from adsorption measurements. Presented at the 15th International Symposium on Chromatography, Nürnberg, October 1984
Keywords:Thin-layer chromatography  Adsorption equilibrium constant  Thermodynamics approach to TLC
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