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Designable Guest-Molecule Encapsulation in Metal–Organic Frameworks for Proton Conductivity
Authors:Feng-Dong Wang  Bin-Cheng Wang  Biao-Biao Hao  Prof Chen-Xi Zhang  Prof Qing-Lun Wang
Institution:1. College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin, 300457 P. R. China

College of Chemistry, and Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071 P. R. China;2. College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin, 300457 P. R. China;3. College of Chemistry, and Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071 P. R. China

Abstract:Metal–organic frameworks (MOFs), as a porous frame material, exhibit considerable electrical conductivity. In recent decades, research on the proton conductivity of MOFs has made gratifying progress. In this review, the designable guest molecules encapsulated into MOFs are summarized and generalized into four types in terms of promoting proton conductive performance, and then recent progress in the promotion of proton conductivity by MOFs encapsulating guest molecules is discussed. The existing challenges and prospects for the development of this strategy for promoting MOFs’ proton conductivity are also listed.
Keywords:designable guest molecules  encapsulation  metal–organic frameworks  proton conductivity
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