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Towards the Development of a Selective Ruthenium‐Catalyzed Hydroformylation of Olefins |
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| Authors: | Dr Ivana Fleischer Lipeng Wu Irina Profir Dr Ralf Jackstell Prof Dr Robert Franke Prof Matthias Beller |
| Institution: | 1. Leibniz Institut für Katalyse e.V. an der Universit?t Rostock, Albert‐Einstein‐Strasse 29a, 18059 Rostock (Germany), Fax: (+49)?381‐1281‐51113;2. Evonik Industries AG, Paul‐Baumann‐Strasse 1, 45772 Marl (Germany);3. Lehrstuhl für Theoretische Chemie, 44780 Bochum (Germany) |
| Abstract: | The ruthenium‐catalyzed hydroformylation of 1‐ and 2‐octene to give preferentially the corresponding linear aldehyde is reported. The catalyst system comprising of Ru3(CO)12 and an imidazole‐substituted monophosphine ligand allows for high chemo‐ and regioselectivity. The hydroformylation proceeds with unprecedented rates for a ruthenium‐based catalyst. |
| Keywords: | aldehydes carbonylation hydroformylation phosphine ruthenium |