Facile Synthesis of Quasi‐One‐Dimensional Au/PtAu Heterojunction Nanotubes and Their Application as Catalysts in an Oxygen‐Reduction Reaction

An intermediate‐template‐directed method has been developed for the synthesis of quasi‐one‐dimensional Au/PtAu heterojunction nanotubes by the heterogeneous nucleation and growth of Au on Te/Pt core–shell nanostructures in aqueous solution. The synthesized porous Au/PtAu bimetallic nanotubes (PABNTs) consist of porous tubular framework and attached Au nanoparticles (AuNPs). The reaction intermediates played an important role in the preparation, which fabricated the framework and provided a localized reducing agent for the reduction of the Au and Pt precursors. The Pt₇Au PABNTs showed higher electrocatalytic activity and durability in the oxygen‐reduction reaction (ORR) in 0.1 M HClO₄ than porous Pt nanotubes (PtNTs) and commercially available Pt/C. The mass activity of PABNTs was 218 % that of commercial Pt/C after an accelerated durability test. This study demonstrates the potential of PABNTs as highly efficient electrocatalysts. In addition, this method provides a facile strategy for the synthesis of desirable hetero‐nanostructures with controlled size and shape by utilizing an intermediate template.