Supercubooctahedron (Cs6Cl)2Cs5[Ga15Ge9Se48] Exhibiting Both Cation and Anion Exchange |
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| Authors: | Shang‐Xiong Huang‐Fu Jin‐Ni Shen Prof Hua Lin Prof Ling Chen Prof Li‐Ming Wu |
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| Institution: | 1. Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (P. R. China);2. University of Chinese Academy of Sciences, Beijing, 100039 (P. R. China) |
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| Abstract: | A novel type of supertetrahedral connectivity is exhibited by the 72‐atom discrete supercubooctahedron in (Cs6Cl)2Cs5Ga15Ge9Se48] ( 1 ), which undergoes both cation and anion exchange, as revealed by unambiguous single‐crystal X‐ray diffraction data. Electronic‐structure studies helped to understand the Ge/Ga distribution. |
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| Keywords: | chalcogenides cluster compounds ion exchange solid‐state reactions solid‐state structures |
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