On Structural Features Necessary for Near‐IR‐Light Photocatalysts |
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| Authors: | Dr Gang Wang Prof Baibiao Huang Zhujie Li Prof Zeyan Wang Xiaoyan Qin Prof Xiaoyang Zhang Prof Ying Dai Prof Myung‐Hwan Whangbo |
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| Institution: | 1. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100 (P. R. China);2. School of Physics, Shandong University, Jinan 250100 (P. R. China);3. Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695‐8205 (USA) |
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| Abstract: | In the search for photocatalysts that can directly utilize near‐IR (NIR) light, we investigated three oxides Cu3(OH)4SO4 (antlerite), Cu4(OH)6SO4, and Cu2(OH)3Cl by photodecomposing 2,4‐dichlorophenol over them under NIR irradiation and by comparing their electronic structures with that of the known NIR photocatalyst Cu2(OH)PO4. Both Cu3(OH)4SO4 and Cu4(OH)6SO4 are NIR photocatalysts, but Cu2(OH)3Cl is not. Thus, in addition to the presence of two different CuOm and Cu′On polyhedra linked with Cu?O?Cu′ bridges, the presence of acceptor groups (e.g., SO4, PO4) linked to the metal oxygen polyhedra is necessary for NIR photocatalysts. |
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| Keywords: | copper DFT analysis near IR light photocatalysis polyhedra |
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