Quinonediimine‐Induced Oxidative Coupling of Organomagnesium Reagents |
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| Authors: | Dr Toru Amaya Riyo Suzuki Prof Dr Toshikazu Hirao |
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| Institution: | Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada‐oka, Suita, Osaka 565‐0871(Japan), Fax: (+81)?6‐6879‐7415 |
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| Abstract: | N,N′‐Diphenyl‐p‐benzoquinonediimine, a redox‐active unit of polyaniline, efficiently induced the oxidative homocoupling of various aryl‐ and vinylmagnesium reagents in suppressing the side reactions, such as 1,2‐ or 1,4‐addition reaction. |
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| Keywords: | C C coupling electron transfer Grignard reaction oxidation redox chemistry |
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