A New Biscarbazole-Based Metal–Organic Framework for Efficient Host–Guest Energy Transfer |
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| Authors: | Qianqian Mu Jingjuan Liu Weiben Chen Xiaoyu Song Xiaoting Liu Prof Xiaotao Zhang Prof Ze Chang Prof Long Chen |
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| Institution: | 1. Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Science and Institute of Molecular Plus, Tianjin University, Tianjin, 300072 P. R. China;2. School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecular-Based Material Chemistry, Nankai University, Tianjin, 300350 P. R. China |
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| Abstract: | A new metal–organic framework (MOF), Zn6L4(Me2NH2+)4⋅3 H2O] ( 1 ) was constructed based on 9, 9′-biscarbazole]-3, 3′, 6, 6′-tetracarboxylic acid (H4L) and Zn2+ ions. The porous framework and intense blue fluorescence of the MOF based on the biscarbazole moiety of the ligand could facilitate efficient host to guest energy transfer, which makes it an ideal platform for the tuning of luminescence. |
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| Keywords: | energy transfer fluorescence host–guest systems in situ encapsulation metal–organic frameworks |
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