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Porphyrins and Polyoxometalate Scaffolds
Authors:Dr Raphaël Lamare  Dr Romain Ruppert  Prof Corinne Boudon  Prof Laurent Ruhlmann  Dr Jean Weiss
Institution:Institut de Chimie de Strasbourg, UMR 7177 CNRS-Université de Strasbourg, 4, rue Blaise Pascal, 67000 Strasbourg, France
Abstract:Polyoxometalates (POMs) can act as unique reservoirs for multiple electron transfers. As POMs display only weak absorption in the visible spectrum, they can be associated with chromophores such as porphyrins and porphyrin antennae. In this Minireview, the research dedicated to the combination of porphyrins and polyoxometalates is put in context and the state of the art identifying the challenges addressed in the optimization of hybrid materials for applications is detailed.
Keywords:Electrochemistry  Photochemistry  Porphyrins  Polyoxometalates  Self-Organization
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