Organometallphosphin-substituierte übergangsmetallkomplexe XVII. Tetracarbonyl-di(organometallphosphin)-chrom-, -molybdän- und -wolfram-komplexe |
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Authors: | Herbert Schumann Joachim Opitz |
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Institution: | Institut für Anorganische and Analytische Chemie der Technischen Universität Berlin, Berlin Deutschland |
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Abstract: | Bicyclo2.2.1]-2,5-heptadiene complexes of transition metal carbonyls have been treated with organometallic phosphines, to give the disubstituted compounds (R3M′)3P]2M(CO)4 R = CH3; M′ = Ge, Sn; M = Cr, Mo, W] by exchange of ligands. The chemical and spectroscopic properties of the new compounds are reported. |
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Keywords: | For correspondence |
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