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The reaction of allene with β-diketonatoiridium(I) complexes: formation and crystal structure of a new bis-β-allylic derivative of iridium(III) |
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| Authors: | P Diversi G Ingrosso A Immirzi M Zocchi |
| Institution: | Istituto di Chimica Organica Industriale, Università di Pisa, Via Risorgimento 35, 56100 Pisa Italy;Istituto di Chimica delle Macromolecole del C.N.R., Via A. Corti 12, 20133 Milano Italy;Istituto di Chimica Industriale, Sezione di Chimica Macromolecolare e Materiali, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano Italy |
| Abstract: | The reaction of allene with (Hfacac)Ir(η-C8H14)2 to give a new bis-η-allylic complex of iridium(III) containing an allene tetramer is described; the X-ray structure of this compound is reported. |
| Keywords: | To whom correspondence should be addressed |
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