The electrochemical preparation of organo nickel and palladium halides |
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| Authors: | Jacob J Habeeb Dennis G Tuck |
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| Institution: | Department of Chemistry, University of Windsor, Windsor, Ontario N9B 3P4 Canada |
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| Abstract: | The electrochemical oxidation of a nickel or palladium anode in the presence of certain organic halides yields the unstable RMX species, which can be stabilised by both mono and bidentate phosphorus(III) ligands. Cyanide compounds of the general formula RNiCN.L2 can also be synthesised. The advantages of the method are outlined. |
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