Synthesis of novel rhodium phosphite catalysts for efficient and selective isomerization-hydroformylation reactions |
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| Authors: | Irene Piras Ralf Jackstell Anke Spannenberg Klaus-Diether Wiese |
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| Institution: | a Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29 A, 18059 Rostock, Germany
b OXENO Olefinchemie GmbH, Marl, Germany |
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| Abstract: | New modular H8-BINOL-based phosphite ligands have been synthesized. High activity and regioselectivity has been achieved in the rhodium-catalyzed isomerization-hydroformylation of internal olefins. The active catalysts have been characterized by insitu NMR studies. |
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| Keywords: | Homogeneous catalysis Isomerization Hydroformylation Bisphosphites Rhodium |
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