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Relative stability of η-cyclopentadienyl(olefin)ruthenium cations: The first estimation of the nature of the Ru-olefin bond |
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| Authors: | Kenzo Ohkita Hideo Kurosawa Toshikazu Hirao Isao Ikeda |
| Institution: | Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565 Japan |
| Abstract: | Relative stability in coordination of substituted styrene derivatives to Ru(η-C5H5)(dtpe)]+ (dtpe = 1,2-bis(di-p-tolylphosphino)-ethane) was determined by NMR spectroscopy to reveal unusually weak substituent dependency of the stability. |
| Keywords: | Ruthenium Olefin Cyclopentadienyl Bond nature |
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