First structurally characterized triazinyl palladium complexes via oxidative addition of cyanuric chloride derivatives |
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| Authors: | Markus Braun |
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| Institution: | Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstr. 1, 40225 Düsseldorf, Germany |
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| Abstract: | The reaction of cyanuric chloride and two disubstituted derivatives with Pd(PPh3)4] is described, leading to the trans-triazinyl complexes (PPh3)2Pd(C3N3R2)Cl] 2a-c (R = Ph (a), t-Bu (b), Cl (c)) in good to excellent yield via oxidative addition. The complexes were fully characterized including X-ray structure determination. |
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| Keywords: | Palladium Cyanuric chloride Triazine Oxidative addition |
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