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Formation of [Cp2TiSbMe2]2, [Cp2TiSb(SiMe3)2]2 and [Cp2TiCl]2·2Mes4Sb2 |
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| Authors: | HJ Breunig O Moldovan U Rosenthal RA Varga |
| Institution: | a Institut für Anorganische und Physikalische Chemie, Universität Bremen, Fachbereich 2, Postfach 330 440, D-28334 Bremen, Germany b Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29A, D-18059 Rostock, Germany c Facultatea de Chimie si Inginerie Chimica, Universitatea Babes-Bolyai, 11 Arany Janos, 400028 Cluj-Napoca, Romania |
| Abstract: | Reactions of Cp2Ti(btmsa)] (btmsa = bis(trimethylsilyl)acetylene) with R4Sb2 (R = Me, Me3Si) give Cp2TiSbMe2]2 (1) or Cp2TiSb(SiMe3)2]2 (2) respectively. Cp2TiCl]2·2Mes4Sb2 (3) is serendipitously formed from Cp2Ti(btmsa)] and Mes2SbH containing NH4Cl traces. |
| Keywords: | Antimony Titanium X-ray diffractometry |
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