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Heck reactions with various types of palladium complex catalysts: application of multiphase catalysis and supercritical carbon dioxide
Authors:Bhalchandra M Bhanage
Institution:Division of Materials Science and Engineering, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan
Abstract:The application of multiphase catalytic systems for palladium catalyzed Heck reactions brings several benefits such as easy catalyst-product separation and catalyst recycling. The effective multiphase Heck systems can be prepared by using different types of catalyst phases, including biphasic catalysis and supported liquid phase catalysts, and a new generation solvent of supercritical carbon dioxide.
Keywords:Heck reaction  Biphasic catalysis  Supported liquid phase catalyst  Supercritical carbon dioxide
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