Preparation and properties of molybdenum and tungsten dinitrogen complexes : `XVI. Electrochemical properties of tungsten and molybdenum diazoalkane complexes |
| |
| Authors: | Yasushi Mizobe Reiko Ono Yasuzo Uchida Masanobu Hidai Meguru Tezuka Suehiro Moue Atsuhiko Tsuchiya |
| |
| Institution: | Department of Industrial Chemistry, University of Tokyo, Hongo, Tokyo 113 Japan;Department of Environmental Engineering, The Saitama Institute of Technology, Fusasiji, Okabe, Saitama 369-02 Japan |
| |
| Abstract: | Diazoalkane complexes of type MF(NNCRR′)(dpe)2]BF4] (M = Mo or W; dpe = Ph2PCH2CH2PPh2), which are easily derived from bis(dinitrogen) complexes M(N2)2(dpe)2], undergo consecutive one- and two-electron oxidations and reductions under voltammetric conditions at a platinum electrode. The ESR spectra of the species generated by the controlled potential electrolysis show that primary oxidation occurred on the metal atom (M = Mo) and reduction on the two nitrogen atoms in the diazoalkane ligands (M = Mo or W). |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
