Studies on ferrocene derivatives XIX. The acylation of [m]-ferrocenophanes and 1,1′-diethylferrocene and the direct conversion of the acylferrocenes to ethers and alkenes |
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| Authors: | Ronald G Sutherland John R Sutton William H Horspool |
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| Institution: | Department of Chemistry and Chemical Engineering, The University of Saskatchewan, Saskatoon S7N0W0 Canada;Department of Chemistry, The University, Dundee Great Britain |
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| Abstract: | The Vilsmeir formylation of 1,1′-diethylferrocene, 3]- and 4]ferrocenophane has been shown to produce mainly, but not exclusively, the β-isomer and the ratio of β/α for the acetylation of 3]-ferrocenophane depends on the reagent used in the reaction. These aldehydes are directly converted to ethers by reduction with sodium borohydride in alcohol and also to alkenes via the Wittig reaction. |
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