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Unexpected isolation and structural characterization of a redox-active Fe(II) piano-stool complex with an η-dppe ligand |
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| Authors: | Safaa Ibn Ghazala Frédéric Paul Loic Toupet Claude Lapinte |
| Institution: | a Sciences Chimiques de Rennes, Université de Rennes I, CNRS (UMR 6226), Campus de Beaulieu, Bât. 10C, 35042 Rennes, France b Groupe Matière Condensée et Matériaux, Université de Rennes I, CNRS (UMR 6626), Campus de Beaulieu, 35042 Rennes, France |
| Abstract: | A new cationic complex (η2-bipy)(η5-C5Me5)Fe(η1-dppe)]BPh4] featuring a pendant free diphenylphosphine arm has been isolated in good yield after reaction of 2,2′-bipyridine with the known chloro precursor complex (η2-dppe)(η5-C5Me5)FeCl in presence of NaBPh4. This complex which can be envisioned as a new redox-active building-block has been structurally characterized. |
| Keywords: | Piano-stool Iron(II) complex 2 2&prime -Bipyridine η1-Diphosphine Redox-active |
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